Tolerancing of centering of a reflective dual field-of-view optical system based on Alvarez-Principle

A new dual state reflective optical relay system based on the Alvarez principle is proposed, which can be used for remote sensing applications. Using the solution found, two different object fields can be imaged using the same optical system. A Three-Mirror-Anastigmat telescope (TMA) is proposed with an intermediate image plane that incorporates a double reflective freeform subsystem as a relay system. By mechanically moving two freeform mirror substrates, this subsystem allows for a discrete change in the total focal length. A deep understanding of the effects of geometric deviations on the system is a crucial prerequisite for ensuring mechanical feasibility and stable optical imaging performance. For this reason, this article focuses on the method and results of tolerancing the subsystem

Precision manufacturing of a lightweight mirror body made by selective laser melting

This article presents a new and individual way to generate opto-mechanical components by Additive Manufacturing, embedded in an established process chain for the fabrication of metal optics. The freedom of design offered by additive techniques gives the opportunity to produce more lightweight parts with improved mechanical stability. The latter is demonstrated by simulations of several models of metal mirrors with a constant outer shape but varying mass reduction factors. The optimized lightweight mirror exhibits $63.5 \%$ of mass reduction and a higher stiffness compared to conventional designs, but it is not manufacturable by cutting techniques. Utilizing Selective Laser Melting instead, a demonstrator of the mentioned topological non-trivial design is manufactured out of AlSi12 alloy powder. It is further shown that -- like in case of a traditional manufactured mirror substrate -- optical quality can be achieved by diamond turning, electroless nickel plating, and polishing techniques, which finally results in $< 150$~nm peak-to-valley shape deviation and a roughness of $< 1$~nm rms in a measurement area of $140 \times 110$ $\mu$m${}^2$. Negative implications from the additive manufacturing are shown to be negligible. Further it is shown that surface form is maintained over a two year storage period under ambient conditions.Comment: 13 pages, 19 figures, online version (corrected proof

New Perspectives for Evaluating the Mass Transport in Porous Catalysts and Unfolding Macro- and Microkinetics

In this article we shed light on newly emerging perspectives to characterize and understand the interplay of diffusive mass transport and surface catalytic processes in pores of gas phase metal catalysts. As a case study, nanoporous gold, as an interesting example exhibiting a well-defined pore structure and a high activity for total and partial oxidation reactions is considered. PFG NMR (pulsed field gradient nuclear magnetic resonance) measurements allowed here for a quantitative evaluation of gas diffusivities within the material. STEM (scanning transmission electron microscopy) tomography furthermore provided additional insight into the structural details of the pore system, helping to judge which of its features are most decisive for slowing down mass transport. Based on the quantitative knowledge about the diffusion coefficients inside a porous catalyst, it becomes possible to disentangle mass transport contributions form the measured reaction kinetics and to determine the kinetic rate constant of the underlying catalytic surface reaction. In addition, predictions can be made for an improved effectiveness of the catalyst, i.e., optimized conversion rates. This approach will be discussed at the example of low-temperature CO oxidation, efficiently catalysed by npAu at 30 °C. The case study shall reveal that novel porous materials exhibiting well-defined micro- and mesoscopic features and sufficient catalytic activity, in combination with modern techniques to evaluate diffusive transport, offer interesting new opportunities for an integral understanding of catalytic processes

Design of an imaging spectrometer for Earth observation using freeform mirrors

Design of an imaging spectrometer for earth observation using freeform mirrors Thomas Peschel1, Christoph Damm1, Matthias Beier1, Andreas Gebhard1, Stefan Risse1, Ingo Walter2, Ilse Sebastian2, David Krutz2 1 Fraunhofer Institut für Angewandte Optik und Feinwerktechnik, Jena 2 DLR, Institut für Optische Sensorsysteme, Berlin In 2017 the new hyperspectral DLR Earth Sensing Imaging Spectrometer (DESIS) will be integrated in the Multi-User-System for Earth Sensing (MUSES) platform /1/ installed on the International Space Station (ISS). The DESIS instrument is developed under the responsibility of the DLR. It will deliver images of the earth with a spatial resolution of 30 m on ground in 235 spectral channels in the wavelength range from 400 nm to 1 µm. As partner of the development team Fraunhofer IOF is responsible for the optical system of the imaging spectrometer.The optical system is made of two primary components: A compact Three-Mirror-Anastigmat (TMA) telescope images the ground strip under observation onto a slit. The following spectrometer reimages the slit onto the detector and performs the spectral separation using a reflective grating. The whole optical system is realized using metal-based mirrors the surfaces of which are made by Single-Point-Diamond Turning (SPDT). Since the spectral range is in the visible, a post-processing of the surfaces by Nickel plating is necessary. The final surface shape and roughness are realized by a second SPDT step and subsequent Magneto-Rheological Finishing. The TMA provides a focal length of 320 mm and an aperture of F/2.8. Its mechanical design relies on the Duolith-technology of IOF as well as optical and mechanical reference structures on the mirrors /2/ manufactured in the same SPDT run. This strategy allows for a significantly simplified adjustment of the optical system /3/. The spectrometer was designed on the basis of the so-called Offner scheme. Because of the high aperture of the system a freeform mirror had to be introduced in order to provide a good imaging quality over the whole spectral range. The above optical design requires a grating on a curved surface. Technologies are developed in order to fabricate the grating either by SPDT or, alternatively, by laser lithography. The mechanical design uses light-weight housing elements which wrap the optical path to suppress stray light. An athermal design is provided by using the same metal for mirrors and housing. To provide high adjustment precision, the housing elements carry reference and mounting features made by SPDT as well. This approach allows for a stiff mechanical set-up of the system, which is compatible with the harsh requirements of a space flight. References: 1 N. Humphrey, “A View From Above: Imaging from the ISS”, Teledyne DALSA 2014, http://possibility.teledynedalsa.com/a-view-from-above/ 2 S. Scheiding, e.a., “Ultra-precisely manufactured mirror assemblies with well-defined reference structures“, Proc. SPIE 7739, 2010. 3 T. Peschel, e.a., “Anamorphotic telescope for earth observation in the mid-infrared range”, ICSO 201